| PES ID | FIFA ID | # | Player | Nationality | Height | Weight | Strong Foot | Team Name(s) |
|---|---|---|---|---|---|---|---|---|
| 43094 | 201153 | 7 | CF Álvaro Morata | Spain | 189cm | 85kg | Right | AC Milan, Spain |
| 47522 | - | 24 | CB Aymeric Laporte | Spain | 191cm | 86kg | Left | Al Nassr FC, Spain |
| 100809 | - | 26 | CF Ayoze Pérez | Spain | 179cm | 66kg | Right | Villarreal A, Spain |
| 101058 | - | 3 | LB Alejandro Grimaldo | Spain | 171cm | 69kg | Left | Bayer 04 Leverkusen, Spain |
| 101520 | 220901 | 1 | GK David Raya | Spain | 183cm | 80kg | Right | Arsenal FC, Spain |
| 103613 | 225193 | 6 | CMF Mikel Merino | Spain | 189cm | 83kg | Left | Arsenal FC, Spain |
| 106956 | 227127 | 13 | GK Álex Remiro | Spain | 191cm | 80kg | Right | Vasco Gipuzkoa AB, Spain |
| 106957 | 230869 | 23 | GK Unai Simón | Spain | 190cm | 89kg | Right | Bilbao BR, Spain |
| 108239 | 226271 | 8 | CMF Fabián Ruiz | Spain | 189cm | 70kg | Left | Paris Saint-Germain, Spain |
| 109101 | 228813 | 15 | CMF Aleix García | Spain | 173cm | 68kg | Right | Bayer 04 Leverkusen, Spain |
| 110596 | - | 21 | CF Mikel Oyarzabal | Spain | 181cm | 78kg | Left | Vasco Gipuzkoa AB, Spain |
| 110815 | 231866 | 16 | DMF Rodri | Spain | 190cm | 82kg | Right | Manchester B, Spain |
| 110902 | 244260 | 10 | AMF Dani Olmo | Spain | 179cm | 72kg | Right | FC Barcelona, Spain |
| 112009 | 233486 | 5 | CB Robin Le Normand | Spain | 187cm | 81kg | Right | Madrid Rosas RB, Spain |
| 116575 | 239231 | 25 | LB Marc Cucurella | Spain | 174cm | 69kg | Left | Chelsea B, Spain |
| 116751 | 241461 | 22 | LWF Ferran Torres | Spain | 184cm | 77kg | Right | FC Barcelona, Spain |
| 119828 | 243576 | 2 | RB Pedro Porro | Spain | 176cm | 71kg | Right | Tottenham WB, Spain |
| 126426 | - | 14 | RB Óscar Mingueza | Spain | 184cm | 75kg | Right | Vigo AB, Spain |
| 130202 | - | 18 | DMF Martín Zubimendi | Spain | 181cm | 74kg | Right | Arsenal FC, Spain |
| 133157 | 251854 | 20 | CMF Pedri | Spain | 174cm | 60kg | Right | FC Barcelona, Spain |
| 134758 | 257279 | 17 | LMF Álex Baena | Spain | 175cm | 70kg | Right | Madrid Rosas RB, Spain |
| 142261 | 256516 | 11 | LWF Nico Williams | Spain | 181cm | 69kg | Right | Bilbao BR, Spain |
| 147235 | 264240 | 9 | CMF Gavi | Spain | 173cm | 70kg | Right | FC Barcelona, Spain |
| 159586 | - | 12 | CB Dean Huijsen | Spain | 196cm | 86kg | Right | Madrid Chamartin B, Spain |
| 162114 | 277643 | 19 | RWF Lamine Yamal | Spain | 180cm | 72kg | Left | FC Barcelona, Spain |
| 165696 | 278046 | 4 | CB Pau Cubarsí | Spain | 184cm | 75kg | Right | FC Barcelona, Spain |